Complete
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6 8 10 13 16 19 21 7 1 18 17 2 9 15 14 3 12 20 11 4 5
  1. 1 a English-American Hollywood star, born Alexander Archibald Leach, d.1986 (4,5)
  2. 8 a Be of use to (5)
  3. 9 a Island where Napoleon was born (7)
  4. 10 a Church service in late afternoon (8)
  5. 11 a A biped has two (4)
  6. 13 a Been there, done that and bought this? (1-5)
  7. 14 a Car part (6)
  8. 16 a Those few who stay on after the others have left or been forced out (4)
  9. 17 a Sounding sheepish? (8)
  10. 19 a War paint for eyelashes? (7)
  11. 20 a Should (5)
  12. 21 a Over (9)
  13. 1 d Painful facial lump or blister (4,4)
  14. 2 d Formally disavow a belief once held (6)
  15. 3 d What might develop into something substantial? (4)
  16. 4 d Place's rising (anag) — Australian town (5,7)
  17. 5 d A riot's target (anag) — Tower of London entrance from the Thames (8,4)
  18. 6 d Accept my word for it! (4,2,4,2)
  19. 7 d Accept the consequences of one's actions (4,3,5)
  20. 12 d Barely manage (3,5)
  21. 15 d Acid neutraliser (6)
  22. 18 d Penny ___ (1967 Beatles song) (4)

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